发信人: zjliu (秋天的萝卜), 信区: Chemistry
标 题: 化学程序的补充说明 2
发信站: BBS 哈工大紫丁香站 (Fri Sep 17 09:23:33 2004)
发信站: 日月光华
如何让计算气体反应的程序来计算溶液反应。
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<title>How to calculate ion Balance</title>
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<h1 align="center"><a name="Contents"></a><em> How to calculate Ion
Balance</em></h1>
Balance</em></h1>
<p>We found that the program <em>Chemical Balance of Gases</em>
can also solve solution problems because of the pressure unit <em>Atm</em>.
Under constant temperature and constant volume, pressure also
stands for the consistence. You can substitute <em>Atm</em> to <em>Mol/L</em>
without changing the <em>Balance Constant, </em>for both unit <em>Atm</em>
in gases and <em>Mol/L</em> in solution can be standard unit. But
the <em>Amount</em> and <em>Volume</em> have no such relations in
solution. So don't give the correct amount or correct volume. If
you have to use amount and volume and you know the balance
constant, be sure to change the temperature to 12.18667K. Under
this temperature, one <em>Atm</em> equals to one <em>Mol/L</em>.</p>
<p>The following is an example about the Ion Balance
HAc=H<sup>+</sup>+Ac<sup>-</sup>.</p>
<table border="0">
<tr>
<td align="center"><table border="1" width="100%">
<tr>
<td><p align="left">Temperature:</p>
</td>
</td>
<td><p align="left"><input type="text" size="10"
name="Temperature" value="12.18667"></p>
</td>
<td><p align="left"><select name="T_Unit"
size="1">
<option selected value="0">K</option>
<option value="273.15">`C</option>
</select></p>
</td>
</tr>
</table>
</td>
<td align="center" rowspan="2"><table border="1">
<tr>
<td><p align="left">Balance Constant</p>
</td>
</tr>
<tr>
<td><p align="left">K=<input type="text"
size="10" name="K" value="1.77827941003892E-05"></p>
</td>
</tr>
</tr>
<tr>
<td>pK=<input type="text" size="10" name="pK"
value="4.75"></td>
</tr>
</table>
</td>
</tr>
<tr>
<td align="center"><table border="1">
<tr>
<td align="center"> </td>
<td align="center"><p align="left"><input
type="text" size="3" name="A_Mol" value="1"> <input
type="text" size="5" name="A_Name" value="HAc"><input
type="checkbox" checked name="A_Gas" value="ON"></p>
</td>
<td align="center"><p align="left">+</p>
</td>
<td align="center"><p align="left"><input
type="text" size="3" name="B_Mol" value="0"> <input
type="text" size="5" name="B_Name"><input
type="checkbox" name="B_Gas" value="ON"></p>
type="checkbox" name="B_Gas" value="ON"></p>
</td>
<td align="center"><p align="left">=</p>
</td>
<td align="center"><p align="left"><input
type="text" size="3" name="D_Mol" value="0"> <input
type="text" size="5" name="D_Name" value="H(+)"><input
type="checkbox" checked name="D_Gas" value="ON"></p>
</td>
<td>+</td>
<td><input type="text" size="3" name="E_Mol"
value="0"><input type="text" size="5"
name="E_Name" value="Ac(-)"><input
type="checkbox" checked name="E_Gas" value="ON"></td>
</tr>
</table>
</td>
</tr>
<tr>
<td align="center" colspan="2"><table border="1">
<tr>
<td colspan="8"><p align="left">Reaction under
Constant Volume: <input type="text" size="10"
Constant Volume: <input type="text" size="10"
name="Volume_React" value="1"> <select
name="Volume_Unit" size="1">
<option selected value="0.001">L</option>
<option value="1">m^3</option>
<option value="0.000001">mL</option>
</select></p>
</td>
</tr>
<tr>
<td> </td>
<td><p align="left"><input type="text" size="5"
name="A_Name_Pressure" value="HAc"><select
name="AP_Unit" size="1">
<option value="0">mol</option>
<option selected value="101325">atm</option>
<option value="133.322">mmHg</option>
<option value="1">Pa</option>
</select></p>
</td>
<td><p align="left"><input type="text" size="5"
name="B_Name_Pressure"><select name="BP_Unit"
size="1">
size="1">
<option selected value="0">mol</option>
<option value="101325">atm</option>
<option value="133.322">mmHg</option>
<option value="1">Pa</option>
</select></p>
</td>
<td><p align="left"><input type="text" size="5"
name="C_Name_Pressure" value="H(+)"><select
name="CP_Unit" size="1">
<option value="0">mol</option>
<option selected value="101325">atm</option>
<option value="133.322">mmHg</option>
<option value="1">Pa</option>
</select></p>
</td>
<td><p align="left"><input type="text" size="5"
name="D_Name_Pressure" value="Ac(-)"><select
name="DP_Unit" size="1">
<option value="0">mol</option>
<option selected value="101325">atm</option>
<option value="133.322">mmHg</option>
<option value="1">Pa</option>
<option value="1">Pa</option>
</select></p>
</td>
<td>Total: <select name="TP_Unit" size="1"
onchange="Calc_Total">
<option value="0">mol</option>
<option selected value="101325">atm</option>
<option value="133.322">mmHg</option>
<option value="1">Pa</option>
</select></td>
</tr>
<tr>
<td><p align="left">Pressure</p>
</td>
<td><p align="left"><input type="text" size="10"
name="A0_Pressure" value="1"></p>
</td>
<td><p align="left"><input type="text" size="10"
name="B0_Pressure"></p>
</td>
<td><p align="left"><input type="text" size="10"
name="C0_Pressure"></p>
</td>
</td>
<td><p align="left"><input type="text" size="10"
name="D0_Pressure"></p>
</td>
<td><input type="text" size="10"
name="T0_Pressure" value="1"
onchange="Calc_Total"></td>
</tr>
<tr>
<td><p align="left"><input type="button"
name="React_Pressure" value="React"></p>
</td>
<td><p align="left"><input type="text" size="10"
name="A_Pressure" value=".99579191673547"></p>
</td>
<td><p align="left"><input type="text" size="10"
name="B_Pressure"></p>
</td>
<td><p align="left"><input type="text" size="10"
name="C_Pressure" value="4.20808326452971E-03"></p>
</td>
<td><p align="left"><input type="text" size="10"
name="D_Pressure" value="4.20808326452971E-03"></p>
name="C_Pressure" value="4.20808326452971E-03"></p>
</td>
<td><input type="text" size="10"
name="T_Pressure" value="1.00420808326453"
onchange="Calc_Total"></td>
</tr>
</table>
</td>
</tr>
</table>
<p> </p>
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