Physics 版 (精华区)
发信人: zjliu (秋天的萝卜), 信区: Physics
标 题: Ni团簇的铁电性
发信站: 哈工大紫丁香 (Sat May 24 13:39:57 2003) , 转信
发信站: 瀚海星云
http://www.sciencemag.org/cgi/content/abstract/300/5623/1265
Ferroelectricity in Free Niobium Clusters
Ramiro Moro, Xiaoshan Xu, Shuangye Yin, Walt A. de Heer
Electric deflections of gas-phase, cryogenically cooled, neutral niobium
clusters [NbN; number of atoms (N) = 2 to 150, temperature (T) = 20to
300kelvin], measured in molecular beams, show that cold clusters may attain
an anomalous component with very large electric dipole moments. In
contrast, room-temperature measurements show normal metallic
polarizabilities. Characteristic energies kBTG(N) [Boltzmann constant kB
times a transition temperature TG(N)] are identified, below which the
ferroelectric-like state develops. Generally, TG decreases [110 > TG(N) >
10K] as N increases, with pronounced even-odd alternations for N > 38. This
new state of metallic matter may be related to bulk superconductivity.
School of Physics, Georgia Institute of Technology, Atlanta GA, 30332–0430,
USA.
Volume 300, Number 5623, Issue of 23 May 2003, pp. 1265-1269.
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